Popcorn Polymers in Butadiene Extraction Units
DOI:
https://doi.org/10.21467/ias.13.1.14-21Abstract
Several aspects disturb operation of industrial facilities which can cause severe impact on their efficiency and productivity. In some cases, the impact can expose industrial facilities to serious safety concerns. Therefore, Industrial facilities should always plan to invest in reliability and sustainability of their daily operation. Polymerization is one of the unavoidable risks that can be unpredictable and cause several issues to operating facilities. On the other hand, effective proactive plans can be addressed to minimize and eliminate polymerization risks. This article provides introductory information about polymerization of butadiene “Popcorn polymers”, formation mechanism, associated hazard, control and mitigation methodologies.
Keywords:
Butadiene, Polymerization, PetrochemicalDownloads
References
M. Liang et al., “Oxidation reaction and thermal stability of 1,3-butadiene under oxygen and initiator,” Arabian Journal of Chemistry, vol. 15, no. 11, p. 104289, Nov. 2022, doi: 10.1016/J.ARABJC.2022.104289.
J. M. Hancock, Debby Rossana, and S. J. Korf, “Popcorn in light ends,” Hydrocarbon Engineering, Dec. 2014. Accessed: Feb. 02, 2023. [Online]. Available: https://www.hydrocarbonengineering.com/magazine/hydrocarbon-engineering/december-2014/
L. Li and O. Dogu, “Mitigating butadiene popcorn formation in industrial olefin units,” LABORATORY FOR CHEMICAL TECHNOLOGY, Ghent. Accessed: Feb. 02, 2023. [Online]. Available: https://www.lct.ugent.be/sites/default/files/mastertheses/36.%20Li-Mitigating%20butadiene%20popcorn%20formation%20in%20industrial%20olefin%20units.pdf
French Ministry of the Environment, “Butadiene leak in a petrochemical unit,” Dec. 2000. Accessed: Feb. 02, 2023. [Online]. Available: https://www.aria.developpement-durable.gouv.fr/wp-content/files_mf/A22062_ips22062_002.pdf
EEPC Butadiene Popcorn Issue Group, “Recommendations for Preventing Popcorn in Steam Crackers and Butadiene Plants,” European Ethylene Producers Committee, pp. 1-34, Mar. 2019.
CSB, “Fires and Explosions at TPC Group Port Neches Operations Facility,” Port Neches, Texas, 2020. Accessed: Feb. 02, 2023. [Online]. Available: https://www.csb.gov/assets/1/17/tpc_factual_update_10-29-2020.pdf
M. FERRARA, T. KIM, and C. FERRARA, “Safe removal of polymeric deposits,” Jan. 2015. https://www.digitalrefining.com/article/1001034/safe-removal-of-polymeric-deposits (accessed Feb. 02, 2023).
H.-N. Sun, C. C. Ingram, and J. J. Mcmanus, “Method for inhibiting popcorn polymer formation by heat,” Jan. 24, 1992 Accessed: Feb. 02, 2023. [Online]. Available: https://patentscope.wipo.int/search/en/detail.jsf?docId=WO1992013010
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